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Direct observation of the internal excitation in the products of the two-body recombination of carbon monoxide and tungsten pentacarbonyl

✍ Scribed by Yoichi Ishikawa; Peter A. Hackett; David M. Rayner

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 441 KB
Volume: 145
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80203-3

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✦ Synopsis

A transient infrared spectrum observed following the photolysis of gas phase W (CO), in the presence of CO is shown to be due to internally excited W (CO): formed by the two-body recombination of W(CO)s and CO. The internal excitation is shown to be predominantly vibrational.

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