Trimethylsilyldiazomethane is compared with ethyl diazoacetate for the rhodium, copper, and cobalt catalyzed formation and [2,3] rearrangement of allylsulfonium ylides. At room temperature, the reaction can be carried out using the allyl sulfide as the limiting reagent by slow addition of 3 equivale
β¦ LIBER β¦
Direct observation of the formation and rearrangement of carbene/allyl sulfide ylides
β Scribed by Moss, Robert A.; Ho, Guo Jie; Sierakowski, Claudia
- Book ID
- 126117857
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 305 KB
- Volume
- 114
- Category
- Article
- ISSN
- 0002-7863
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