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Direct observation of nitrogen inversion in free, unprotonated dibenzylmethylamine

✍ Scribed by Bushweller, C. Hackett.; O'Neil, James W.


Book ID
126177154
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
240 KB
Volume
92
Category
Article
ISSN
0002-7863

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A considerable effort has been expended to determine the relative rates of nitrogen inversion and carbon-nitrogen single bond rotation in simple amines, 2 more hindered N-tert-butyl-N,N-dialkylamines, 3 and cyclic amines. 4 Although evidence exists to support concerted tert-butyl rotation and nitrog