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Stereodynamics of multinitrogen heterocycles. I. Direct observation of nitrogen inversion and axial N-methyl groups in N,N',N''-trimethyl-1,3,5-triazane

โœ Scribed by Bushweller, C. Hackett; Lourandos, Marlyn Z.; Brunelle, Jacques A.


Book ID
126209791
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
376 KB
Volume
96
Category
Article
ISSN
0002-7863

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Stereodynamics of N-isopropyl-N,N-dialky
โœ Jean Reny; Chih Y. Wang; C. Hackett Bushweller; Warren G. Anderson ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 198 KB

A considerable effort has been expended to determine the relative rates of nitrogen inversion and carbon-nitrogen single bond rotation in simple amines, 2 more hindered N-tert-butyl-N,N-dialkylamines, 3 and cyclic amines. 4 Although evidence exists to support concerted tert-butyl rotation and nitrog