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Direct observation of multistep decomposition processes of metastable ions

โœ Scribed by E. Tajima; J. Seibl

Publisher
Elsevier Science
Year
1969
Weight
719 KB
Volume
3
Category
Article
ISSN
0020-7381

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Rearrangements in metastable ion decompo
Rearrangements in metastable ion decompositions of protonated propylamines
โœ Henri E. Audier; Thomas Hellman Morton ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 715 KB

Decomposition of nPrNH,+ to NH,+ does not occur via vicinal elimination. Hydrogen transfer takes place from all positions of the alkyl chain. Intermediacy of either an ion-neutral complex, (iPr+ NH,], or rearrangement to iPrNH,+ is required. SCF calculations were used to probe the potential energy s