✦ LIBER ✦

Direct observation of distinctly different rates of rotation and inversion in N-tert-butyl-N-benzylchloramine

✍ Scribed by C.Hackett Bushweller; James W. O'Neil

Book ID: 104248135
Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 179 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)97208-9

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

The rotation-inversion dichotomy in tria

The rotation-inversion dichotomy in trialkylamines. Direct proton DNMR observation of distinctly different rates of nitrogen inversion and carbon-nitrogen bond rotation in isopropylmethylethylamine

✍ Bushweller, C. Hackett; Wang, Chih Y.; Reny, Jean; Lourandos, Marilyn Z. 📂 Article 📅 1977 🏛 American Chemical Society 🌐 English ⚖ 418 KB

Stereodynamics of N-tert-butyl-N-haloami

Stereodynamics of N-tert-butyl-N-haloamines. Experimental and theoretical investigations of nitrogen inversion and tert-butyl rotation. Dynamical model for the rotation-inversion dichotomy in all alkylamines

✍ Bushweller, C. Hackett; Anderson, Warren G.; Stevenson, Philip E.; O'Neil, James 📂 Article 📅 1975 🏛 American Chemical Society 🌐 English ⚖ 769 KB

Stereodynamics of multinitrogen heterocy

Stereodynamics of multinitrogen heterocycles. I. Direct observation of nitrogen inversion and axial N-methyl groups in N,N',N''-trimethyl-1,3,5-triazane

✍ Bushweller, C. Hackett; Lourandos, Marlyn Z.; Brunelle, Jacques A. 📂 Article 📅 1974 🏛 American Chemical Society 🌐 English ⚖ 376 KB

Reactions of tert-butylsulfinyl chloride

Reactions of tert-butylsulfinyl chloride with tert-butyl hydroperoxide and tert-butyl hydrodisulfide in the presence of pyridine. Observation of 1H CIDNP effects

✍ Ido P. Bleeker; Jan B. F. N. Engberts 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 345 KB

## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis

Modeling of polymerization rate and micr

Modeling of polymerization rate and microstructure in the anionic polymerization of isoprene using n-butyl lithium and N,N,N′,N′-tetramethylethylenediamine considering different reactivities of the structural units

✍ José Alfredo Tenorio-López, Juan José Benvenuta-Tapia… 📂 Article 📅 2012 🏛 Springer 🌐 English ⚖ 362 KB

Nucleophilic character of the alkyl radi

Nucleophilic character of the alkyl radicals. 19. 1a Absolute rate constants in the homolytic alkylation of protonated heteroaromatic bases by n-butyl and tert-butyl radicals

✍ Citterio, Attilio; Minisci, Francesco; Franchi, Valeria 📂 Article 📅 1980 🏛 American Chemical Society 🌐 English ⚖ 786 KB