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Direct Observation of a Photoinduced Radical Pair in a Cryptochrome Blue-Light Photoreceptor

✍ Scribed by Till Biskup; Erik Schleicher; Asako Okafuji; Gerhard Link; Kenichi Hitomi; Elizabeth D. Getzoff; Stefan Weber


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
567 KB
Volume
48
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


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It is shown that 'Jle small molecular contributions to the magnetic-field interaction of a free radical may be obtained directly by magic-doublet rotational Zeeman-effect measurements. Experimental standards normally employed in diamagnetic-molecule work are wholly adequate.

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ESR observation is described of a new type of reaction of alkane radical cations in solid matrices; the cyclobutanc rodi cation in CFCIJ and in SF6 suffers photoinduced ring opening followed by I J-hydride ion transfer to rcarrangc into the but-l-ene radical cation, which further photoisomeiizes int