The room temperature reactions between oxygen atoms and methanethiol, ethanethiol, and methylsulfide have been studied in crossed jets to directly detect and identify the freeradical and stable products they produce. Knowledge of the products was used to assign reactive routes. The overall rate cons
Direct identification of reactive routes in the reaction of oxygen atoms with dimethylamine
โ Scribed by Irene R. Slagle; Joseph F. Dudich; David Gutman
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 475 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0009-2614
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Direct detection of the products of the 0 + C2H3Br reaction occurring in high-intensity room temperature crossed beams reveals that the reaction proceeds by three reactive channels, the products of which are, 1. CH3 + BrCO (and/ or Br + CO); 2. CH2 Br + HCO (and possibly H + CO), and 3. HzCzO + HBr.
The rate constant for the reaction of atomic oxygen (0( 3P)) with dimethylmercury has been measured at room temperature at a pressure of about 1 Tot-r using a fast flow system with electron paramagnetic resonance and mass spectrometric detection. Some reaction products were identified. The rate cons
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