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Direct hydroxylation of fats and derivatives with a hydrogen peroxide tungstic acid system

✍ Scribed by T. M. Luong; H. Schriftman; Daniel Swern


Book ID
112804203
Publisher
Springer-Verlag
Year
1967
Tongue
English
Weight
734 KB
Volume
44
Category
Article
ISSN
0003-021X

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Stereoselective expoxidation of allylic
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The aqueous tungstic acid-catalyzed hydrogen peroxide epoxidation of allyl i c al coho1s affo rds the same major di astereo i somer as the VO( acac) 2/tBu OOH system with quite connarab le stereoselectiviti es . In cont r ast , epoxidatIon of honeallylic al cohol s appears t o be much less stereos e