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Direct formation and subsequent substitution of remote ketone-functionalized organocopper reagents

โœ Scribed by Ebert, Greg W.; Klein, Walter R.

Book ID
127050283
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
530 KB
Volume
56
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Direct formation of functionalized keton
Direct formation of functionalized ketones via the coupling of functionalized organocopper reagents with acid chlorides
โœ Richard M. Wehmeyer; Reuben D. Rieke ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 303 KB

Highly reactive copper solutions have been prepared by the lithium naphthalide reduction of a copper(I) iodide/triphenyl-phosphine complex. These copper solutions react rapidly with functionalized alkyl halides to give organocopper reagents which have been effectively trapped with acid chlorides giv