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Direct determination of the rate constant for the reaction CO + N2O → CO2 + N2

✍ Scribed by Nobuyuki Fujii; Tomohisa Kakuda; Takeo Sugiyama; Hajime Miyama

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
258 KB
Volume
122
Category
Article
ISSN
0009-2614

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✦ Synopsis

The rake cons~~m for lhe bimolecular rexlion CO + N20 -+ CO1 +N2 vzas determined by comparison of calculaled infrared emission profiles of CO? \rirh Ihose observed in shock-Iubc experiments in the lempersture range 1350-2100 K for CO-N?O-He-Ar mixrures. The rate consran~ was found IO be X-, = 3.2 X lO"sxp( -85 kJ/RT) cm3 mol-' s-'.

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The Molecular Structure of CO2–N2O
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Recent microwave studies of N 2 O-containing van der Waals complexes, Ar-N 2 O (1, 2), HCCH-N 2 O (1, 3), CO 2 -N 2 O (4), and 15 N 2 -N 2 O (5), have shown that upon complexation, the electric field gradients at the nitrogen nuclei of N 2 O are perturbed from their values in the free molecule. The