Direct Conversion of Alcohols to α-Chloro Aldehydes and α-Chloro Ketones
✍ Scribed by Jing, Yuanyuan; Daniliuc, Constantin G.; Studer, Armido
- Book ID
- 126453419
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 402 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
Isolable cl-chloro amides are intermediates in the formation of ketones by basic hydrolysis of cl-chloro nitriles. Possible mechanisms for the generation of ketones from cr-chloro amides are discussed. The formation of ketones by basic hydrolysis of cl-chloro nitriles is well known in connection wit
The reactions of sterically less hindered ~z-bromo alkyl and aryl ketones with tetrasulfur tetranitride.antimony pentachloride (S4N4"SbCIj) complex in toluene at reflux gave the corresponding a'-chloro ketones in good to excellent yields.
Reaction of cyclic ~,l~-epoxy ketones with Ce(III) chloride under hydrous or anhydrous conditions yields the corresponding cyclic 0t-chloro-0t,13-enones or cyclic ~-chloro-~-hydroxy ketones, respectively.