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Direct C(1) hydroxylation of vitamin D3 and related compounds

โœ Scribed by Paaren, Herbert E.; DeLuca, Hector F.; Schnoes, Heinrich K.

Book ID
120477874
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
879 KB
Volume
45
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Synthesis of vitamin D3 and related comp
Synthesis of vitamin D3 and related compounds
โœ Tetsuji Kametani; Hiroko Furuyama ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 978 KB

Recently much attention has focused on inducing the hydroxyl group at C-1 and C-25 positions of 1 to obtain the active compound (2, 3, and 4). ## A. From Cholesterol Barton et a1.6 reported in 1973 the convenient synthesis of 1-OH-D3 (3) from la,2a-epoxycholesta-4,6-dien-3-one (8) (obtained from