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Direct Arylation of 6-Phenylpurine and 6-Arylpurine Nucleosides by Ruthenium-Catalyzed CH Bond Activation

✍ Scribed by Prof. Mahesh K. Lakshman; Dr. Ashoke C. Deb; Dr. Raghu Ram Chamala; Dr. Padmanava Pradhan; Dr. Ramendra Pratap


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
391 KB
Volume
50
Category
Article
ISSN
0044-8249

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Activation of Aryl Germanium(II) Chlorid
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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop