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Dipolar relaxations in the glass transition region and in the liquid crystalline phase of two side-chain liquid crystalline polysiloxanes

✍ Scribed by Joaquim J. Moura Ramos; João F. Mano; David Lacey; G. Nestor

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
769 KB
Volume
34
Category
Article
ISSN
0887-6266

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✦ Synopsis

The molecular relaxation mechanisms in the glass transition region and in the liquid crystalline phase exhibited by two side-chain liquid crystalline polysiloxanes have been studied by Thermally Stimulated Discharge Currents. These results were compared with those previously obtained by dielectric relaxation spectroscopy. It was observed that two relaxation mechanisms were present in the liquid crystalline phase, and we suggest that these might correspond to the motions of the mesogenic moieties in the liquid crystalline phase. 0 1996 John Wiley & Sons, Inc.

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