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Diphosphinomethanide/Phosphoniumbismethylide: A Novel Ligand Combination for Transition Metals

✍ Scribed by Prof. Dr. Hubert Schmidbaur; Dr. Johann R. Mandl

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
233 KB
Volume
16
Category
Article
ISSN
0044-8249

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Coordination chemistry of transition met
Coordination chemistry of transition metal complexes of a novel pentadentate ligand
✍ Christian Klarner Sams; Fernando Somoza; Ivan Bernal; Hans Toftlund πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 149 KB

The pentadentate ligand N-(2-pyridylmethyl)-3-(bis(2-pyridylmethyl)amine)-propanamide (LH) and transition metal complexes hereof were synthesised. The negative charge of the deprotonated ligand was meant to stabilise metal ions in high oxidation states thus facilitating aerobic oxidation of the meta