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Diphosphines and Other Phosphines

✍ Scribed by Marcel Schruder Goedheijt; Paul C. J. Kamer; Joost N. H. Reek; Piet W. N. M. van Leeuwen


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ E. SOULIER; J.-C. CLEMENT; J.-J. YAOUANC; H. DES ABBAYES πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 35 KB πŸ‘ 1 views

Reduction of phosphinic acids (I) with phenylsilane or of the corresponding diacids (V) with LiAlH 4 provides phosphines (II) or diphosphines (III) via their acid chlorides. They may be used in Michael additions with the activated alkene (V) or in most cases as stable borane adducts such as (VII) an