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ChemInform Abstract: Diphosphines and Other Phosphines

โœ Scribed by MARCEL SCHREUDER GOEDHEIJT; PAUL KAMER; PIET VAN LEEUWEN

Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Reduction of phosphinic acids (I) with phenylsilane or of the corresponding diacids (V) with LiAlH 4 provides phosphines (II) or diphosphines (III) via their acid chlorides. They may be used in Michael additions with the activated alkene (V) or in most cases as stable borane adducts such as (VII) an