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Dioxiranes. 20. Preparation and properties of some new dioxiranes

✍ Scribed by Murray, Robert W.; Singh, Megh; Jeyaraman, Ramasubbu

Book ID
120355311
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
863 KB
Volume
114
Category
Article
ISSN
0002-7863

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## Abstract Methyl(trifluoromethyl)dioxirane oxidation of natural psoralen (1a) and 8‐methoxypsoralen (8‐MOP, 1b) and dimethyldioxirane oxidation of some related 2,3‐substituted furocoumarins 1c–e at subambient temperature afforded the corresponding labile epoxides 2a–e. The reaction of acetylated