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Dioxidomolybdenum(VI) Complexes Containing Ligands with the Bipyrrolidine Backbone as Efficient Catalysts for Olefin Epoxidation

✍ Scribed by Mayilmurugan, Ramasamy; Traar, Pedro; Schachner, Jörg A.; Volpe, Manuel; Mösch-Zanetti, Nadia C.


Book ID
120433155
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
596 KB
Volume
2013
Category
Article
ISSN
1434-1948

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✍ Swarup K. Maiti; Subhajit Dinda; Ramgopal Bhattacharyya 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 198 KB

A great variety of olefinic substrates having aromatic, carbocyclic and aliphatic olefins are effectively and selectively oxidized with oxygen-rich molybdenum(VI) complexes, namely 5 and [PPh 4 ][Mo(O) 3 -(QO)] 6 (QOH = 8-quinolinol) as catalyst, NaHCO 3 as co-catalyst and H 2 O 2 as the terminal o