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Mesoporous SBA-15 materials modified with oxodiperoxo tungsten complexes as efficient catalysts for the epoxidation of olefins with hydrogen peroxide

โœ Scribed by Jianyuan Tang; Lei Wang; Gang Liu; Yan Liu; Yazhuo Hou; Wenxiang Zhang; Mingjun Jia; Werner R. Thiel


Book ID
103835130
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
807 KB
Volume
313
Category
Article
ISSN
1381-1169

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A great variety of olefinic substrates having aromatic, carbocyclic and aliphatic olefins are effectively and selectively oxidized with oxygen-rich molybdenum(VI) complexes, namely 5 and [PPh 4 ][Mo(O) 3 -(QO)] 6 (QOH = 8-quinolinol) as catalyst, NaHCO 3 as co-catalyst and H 2 O 2 as the terminal o