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Dinuclear Zinc(II)−Iron(III) and Iron(II)−Iron(III) Complexes as Models for Purple Acid Phosphatases

✍ Scribed by Sabine Albedyhl; Marie Therese Averbuch-Pouchot; Catherine Belle; Bernt Krebs; Jean Louis Pierre; Eric Saint-Aman; Stephane Torelli

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
432 KB
Volume
2001
Category
Article
ISSN
1434-1948

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The chemical behavior of two bis(3,5-dialkylpyrazol-1-yl)acetic acids and their coordination properties towards ZnCl 2 and FeCl 2 was studied. Reaction of bis(3,5-dimethylpyrazol-1-yl)acetic acid (bdmpza) (1) with ZnCl 2 and FeCl 2 gave the 2:1 complexes [(bdmpza) 2 Zn] (4) and [(bdmpza) 2 Fe] (5).