𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Dinuclear Rh(II) complexes in styrene hydroformylation. Enhancement of catalytic activity through orthometalation

✍ Scribed by Carmen Claver; Nuria Ruiz; Pascual Lahuerta; Eduardo Peris

Book ID
103108746
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
355 KB
Volume
233
Category
Article
ISSN
0020-1693

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Cooperativity in Rh2 Complexes: High Cat
Cooperativity in Rh2 Complexes: High Catalytic Activity and High Regioselectivity in the Hydroformylation of Olefins
✍ Prof. Dr. Georg SΓΌss-Fink πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 252 KB πŸ‘ 1 views

An important step forward in the search for catalytically active polynuclear metal complexes has been made by George G. Stanley's group: The bimetallic complex cations r~c-[Rh,(nbd),L]~+ l r and rne~o-[Rh,(nbd),L]~+ l m (nbd = norbornadiene) which were isolated as tetrafluoroborates (Scheme l),[l1 w

Bimetallic Hydroformylation Catalysis: I
Bimetallic Hydroformylation Catalysis: In Situ Characterization of a Dinuclear Rhodium(II) Dihydrido Complex with the Largest Rh–HNMR Coupling Constant
✍ Rhonda C. Matthews; Donna K. Howell; Dr. Wei-Jun Peng; Spencer G. Train; Dr. W. πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 557 KB

T = 25 "C, t = 3.5 h) also showed that complex 1 is able to perform more than 36 000 (yield 99.9 YO) without loss of activity. In order to rule out the participation in the catalysis of free, solvated [Rh(PPh,),]+ or similar cationic species formed by dissociation of complex 1, two independent expe