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Dinuclear complexes with a μ-cyano ligand. Part VIII(1). Synthesis and characterization of several derivatives ofcis-[CrX(H2O)(en)2]2+(X=Cl or Br)

✍ Scribed by Joan Ribas; Miquel Serra; Albert Escuer


Publisher
Springer
Year
1984
Tongue
English
Weight
462 KB
Volume
9
Category
Article
ISSN
0340-4285

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.