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Dinuclear complexes with a μ-cyano-ligand. — Part VII. Synthesis and characterization of several derivatives oftrans-[CrF(H2O)(1,2-diaminopropane)2]2+

✍ Scribed by Juan Ribas; María L. Martínez; Miquel Serra; Montserrat Monfort; Albert Escuer; Neus Navarro


Publisher
Springer
Year
1983
Tongue
English
Weight
509 KB
Volume
8
Category
Article
ISSN
0340-4285

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.