✍ Scribed by D. Inman; S.H. White; I. Wilmot(née Regan); B. Jones
No coin nor oath required. For personal study only.
A number of studies have been made of complex ions in molten salts 1'2'13. Particular attention has been paid to the halo-silver complexes in molten nitrate solvents 3. In the latter case, the experimental results have been interpreted in terms of stability constants by the graphical method of Braunstein et al. 4. Braunstein, Blander and their co-workers reported formation constants for dinuclear complexes of the type Ag2 X+ when dilute solutions of silver nitrate in molten alkali nitrates were titrated with chloride 4, bromide 5, iodide 6, or cyanide 7 ions (see Table 1). These studies, and our own on silver-halide complexes in LiC1-KC12 led us to modify the original computational procedure of Inman et al. 8 to include a term in the fitting polynomial to account for the dinuclear complex.
📜 SIMILAR VOLUMES
Thermodynamic activities calculated from solution theories are compared with the values obtained from emf measurements and phase-diagram data on reciprocal molten salt solutions. For the systems examined the experimental results are consistent with theory only if a correction for non-random mixing i
An electrode of the third kmd, respondmg to metal-ion concentration changes m alkahmetal nitrate melts, IS described, and special features and &fficultles attendmg Its practical application are discussed It has been employed to momtor the varymg uncomplexed cadmium ion concentration during titration