An end-off type acyclic ligand with four methoxyethyl chelating arms, 2,6-bis[bis(2-methoxyethyl)aminomethyl]-4methylphenol [H(bomp)], formed dinuclear cobalt(II) complexes [Co 2 (bomp)(MeCO 2 ) 2 ]BPh 4 (1) and [Co 2 (bomp)-(PhCO 2 ) 2 ]BPh 4 (2). X-ray analysis revealed that complex 1•CHCl 3 conta
✦ LIBER ✦
Dinuclear Cobalt(II) Complexes of Pyrazole Ligands with Chelating Side Arms
✍ Scribed by Meyer, Franc ;Beyreuther, Stefan ;Heinze, Katja ;Zsolnai, Laszlo
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 899 KB
- Volume
- 130
- Category
- Article
- ISSN
- 0009-2940
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## Abstract 1,2,4‐Triphenyl‐1,3,5‐triazapentadiene (1a), prepared from benzamidine and __N__‐phenylbenzimidoyl chloride, was treated at room temperature with CoCl~2~, Ni(NO~3~)~2~, Na~2~PdCl~4~, CuCl~2~ and ZnCl~2~ to form the corresponding six‐membered 1:1 chelate complexes 1a·CoCl~2~, 1a·Ni(NO~3~