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Dimsyl Anion Induced Demethylation and Fragmentation Reactions of α-Oxoketenedithioacetals.

✍ Scribed by Satheesh K. Nair; Reichel Samuel; C. V. Asokan


Book ID
101916653
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES


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The chiral α-bromo α,β-unsaturated esters 3 and 9 are react with the kinetic lithium dienolates of enone 10 to give functionalized tricyclo[3.2.1.0 2,7 ]octanes 11. Esters 3 give one prepared by asymmetric Sharpless dihydroxylation (AD) of 5 and from ester 7 and the chiral diols 8 by transacetalizat