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Dimethyl(1,10-phenanthroline)bis(2,3,4,5-tetrafluorobenzoato)tin(IV)

✍ Scribed by Sun, Junshan ;Ma, Chunlin ;Zhang, Rufen

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 498 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807048362

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✦ Synopsis

The title compound, [Sn(CH~3~)~2~(C~7~HF~4~O~2~)~2~(C~12~H~8~N~2~)], was synthesized by the reaction of dimethyltin(IV) dichloride and disodium 2,3,4,5-tetrafluorobenzoate in the presence of 1,10-phenanthroline. In the complex, the Sn^IV^ ion is coordinated by three O atoms of two tetrafluorobenzoate ligands, two N atoms of a 1,10-phenanthroline ligand and two methyl groups in a distorted pentagonal–bipyramidal coordination. The axial positions are occupied by the methyl groups. In the crystal structure, C—H...F and C—H...O hydrogen bonds link the molecules into cyclic centrosymmetric dimers.

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