A new heterotrinuclear macrocyclic complex: bis (ldiethyl 5,6,7,8,15,16-hexahydro-6,7-dioxo-5,8,14,17tetraazadibenzo[a,g]cyclotetradecine-13,18dicarboxylato)-1j 4 N:2j 2 O 6 ,O 7 ;2jO 6 ,O 7 :3j 4 Ndimethanoldinickel(II)zinc(II) bis(perchlorate)
[Dimethyl 5,6,7,8,15,16-hexahydro-6,7-dioxo-5,8,14,17-tetraazadibenzo[a,g]cyclotetradeca-3,9,13,17-tetraene-13,18-dicarboxylato-κ4N,N′,N′′′,N′′′']copper(II)
✍ Scribed by He, Jun-Hong ;Yue, Lei ;Li, Xiao-Zeng ;Zhang, Wen-Qin ;Liu, Bao-Lin
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 140 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A Disorder in solvent or counterion R factor = 0.045 wR factor = 0.101 Data-to-parameter ratio = 15.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu(C 36 H 36 N 4 O 4 )(ClO 4 )](ClO 4 )ÁC 3 H 7 N, the coordination number of the Cu II atom is 5 and the coordination configuration is best described as distorted tetragonal-pyramidal. There is a 13-membered macrocyclic ring in the molecule. One perchlorate anion and the dime