The title compound, C 17 H 19 NO 4 , was synthesized by the Stobbe condensation reaction of p-dimethylaminobenzaldehyde and diethyl succinate, followed by cyclization of the Stobbe product. The crystal structure is stabilized by intermolecular C-HÁ Á Á interactions.
Dimethyl 3,3-dimethoxy-4,4′-methylenedi-2-naphthoate
✍ Scribed by He, Rui ;Gao, En ;Gu, Shao-Jin ;Qin, Da-Bin
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 605 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, C 27 H 24 O 6 , the two naphthalene ring systems are nearly perpendicular to one another with a dihedral angle of 87.77 (2) . The molecular structure is stabilized by several C-HÁ Á ÁO intramolecular hydrogen bonds. In the crystal structure, inversion-related molecules are linked throughinteractions [centroid-centroid distance = 3.6311 (6) A ˚and perpendicular distance between unsubstituted aromatic rings = 3.476 A ˚] between the naphthalene ring systems and also by C-HÁ Á Á interactions. In addition, C-HÁ Á ÁO intermolecular interactions are observed.
📜 SIMILAR VOLUMES
In the title compound, C 19 H 17 BrO 6 , the biphenyl twist angle is 43.6 (1) . All three ester groups are planar and make dihedral angles of 61.0 (1), 70.6 (1) and 14.1 (1) with the attached benzene ring.
The title compound, C 16 H 26 N 2 O 4 Si 2 , is a mesoionic compound of the sydnone class. Its molecular structure reveals the two planar ring fragments mutually twisted by 74.88 (10) . The crystal packing is characterized by a one-dimensional molecular array generated by C-HÁ Á ÁO interactions.