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Dimethyl 3-(benzyl­amino)-2-(4-fluoro­phen­yl)furan-4,5-dicarboxyl­ate

✍ Scribed by Ma, Cheng ;Yang, Yewei


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
231 KB
Volume
61
Category
Article
ISSN
1600-5368

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Dimethyl 2-(4-fluoro­phen­yl)-3-(methyl­
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The title compound, C 16 H 17 NO 5 , crystallizes with two molecules in the asymmetric unit. The dihedral angles between the furan and benzene rings are 26.38 (13) and 28.52 (14) . The molecules are linked by N-HÁ Á ÁO hydrogen bonds, leading to dimers.

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In the molecule of the title compound, C 21 H 28 N 2 O 5 , the substituted 1,4-dihydropyridine (1,4-DHP) ring has a flattened-boat conformation. The carbonyl groups of the ester groups, at positions 3 and 5 in the 1,4-DHP ring, have cis configurations with respect to the double bonds in the 1,4-DHP