Dimethyl 2-(4-fluorophenyl)-3-(methylamino)furan-4,5-dicarboxylate
✍ Scribed by Ma, Cheng ;Yang, Ye-Wei
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 211 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule of compound (1) in the crystal structure. Displacement ellipsoids are drawn at the 50% probability level. The dotted line indicates the intramolecular hydrogen bond.
📜 SIMILAR VOLUMES
The title compound, C 16 H 17 NO 5 , crystallizes with two molecules in the asymmetric unit. The dihedral angles between the furan and benzene rings are 26.38 (13) and 28.52 (14) . The molecules are linked by N-HÁ Á ÁO hydrogen bonds, leading to dimers.
In the molecule of the title compound, C 21 H 28 N 2 O 5 , the substituted 1,4-dihydropyridine (1,4-DHP) ring has a flattened-boat conformation. The carbonyl groups of the ester groups, at positions 3 and 5 in the 1,4-DHP ring, have cis configurations with respect to the double bonds in the 1,4-DHP
In the title compound, C 19 H 20 N 2 O 7 , the C atom in the 4position of the dihydropyridine ring is displaced out of the plane by 0.0461 (2) A ˚. The dihydropyridine ring plane is almost perpendicular to the benzene ring, with a dihedral angle of 88.9 (3) .