3-Phenyl-3-chloro-2-propenthial as Intermediate in the Hydrothiolysis of Dimethyl(3-phenyl-3-chloro-2-propylidene)ammonium Perchlorate. -During hydrothiolysis of the title perchlorate (I), 3-phenyl-3-chloro-2-propenethial is formed intermediately which cannot be isolated neither in pure form nor as
Dimethyl 2-chloro-3-tosylmaleate
✍ Scribed by Abbasi, Alireza ;Kianmehr, Ebrahim ;Beheshti, Saeideh ;Eriksson, Lars
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 696 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 13 H 13 ClO 6 S, contains two methoxycarbonyl groups in a cis arrangement, with a dihedral angle of 79.9 (1) between the least-squares planes defined by the two methoxycarbonyl fragments. Weak van der Waals interactions between the molecules are effective in the molecular packing. This is the first X-ray structure reported for a tosylmaleate derivative which can be used as a pharmaceutical primary material.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.055 wR factor = 0.113 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, C 18 H 15 BrClN 3 O 2 , was obtained by reacting 3-bromo-5-chlorosalicylic aldehyde and 4-aminoantipyrine. The structure displays a trans configuration about the imine C N double bond. The N atom is also involved in an intramolecular O-HÁ Á ÁN hydrogen bond, which stabilizes the
Single-crystal X-ray study T = 295 K Mean (C-C) = 0.004 A R factor = 0.064 wR factor = 0.141 Data-to-parameter ratio = 15.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.