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Dimerization of Terminal Alkynes Catalyzed by a Nickel Complex Having a Bulky Phosphine Ligand.

✍ Scribed by Sensuke Ogoshi; Mizu Ueta; Masa-aki Oka; Hideo Kurosawa


Publisher
John Wiley and Sons
Year
2005
Weight
19 KB
Volume
36
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Ruthenium-Catalyzed
✍ C. SLUGOVC; K. MEREITER; E. ZOBETZ; R. SCHMID; K. KIRCHNER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 1 views

Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex. -The catalytic coupling of alkynes (III) or (VI) in the presence of Ru complexes such as (I) or (II) leads to butenynes with both conversion and selectivity strongly depending on the alkyne substituent.