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Dimerization of Cyclopentadienones

โœ Scribed by Allen, C. F. H.; VanAllan, J. A.


Book ID
126131176
Publisher
American Chemical Society
Year
1950
Tongue
English
Weight
326 KB
Volume
72
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES


Photochemistry of cyclopentadienone dime
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The photochemistry of several cyclopentadienone dimers, & has been reported recently. The excited singlet states of &and l&undergo cl,31 sigmatropic shifts to form & and 2&, while the triplet state of & forms the [2+21 cage isomer 3a.1'2 Recently, Fuchs reported a; R= R/= H b; R=H; R/= Ph c; R= Me;

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## Abstract In continuation of previous work on cyclopentadienone dimers [3], thermal and photochemical interconversions of the isomeric diketones **1, 3**, and **5** by skeletal rearrangements have been established to the extent summarized in schemes 2 and 3, and the intramolecular [2+2] cycloaddi