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Chemical and photochemical behavior of nondissociating cyclopentadienone dimers

✍ Scribed by Fuchs, Benzion; Pasternak, Mordechai; Pazhenchevsky, Barak


Book ID
127048734
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
573 KB
Volume
46
Category
Article
ISSN
0022-3263

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The Photochemical and Thermal Interconve
✍ U. Klinsmann; J. Gauthier; K. Schaffner; M. Pasternak; B. Fuchs πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 German βš– 1019 KB

## Abstract In continuation of previous work on cyclopentadienone dimers [3], thermal and photochemical interconversions of the isomeric diketones **1, 3**, and **5** by skeletal rearrangements have been established to the extent summarized in schemes 2 and 3, and the intramolecular [2+2] cycloaddi

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A&ISCI-The I,(dimethyl-. 1.2.~trimethyl and 12.4.7-letramelhyl subslilultd 3.4o.o'~bipbcnykne) cycbpcntodienoncdimcrs ((14 were prepared and found IO undergo phobchcmically or fkrr~//y a 1.3.reananfcmcnl IO [he ccntrosymmetrical diketons (II). Only the tetnmethyl derivative ((r) undergoes al room le