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Dimerization of aquadioxovanadium(V) ion in concentrated perchloric and sulfuric acid media

✍ Scribed by Madic, C.; Begun, G. M.; Hahn, R. L.; Launay, J. P.; Thiessen, W. E.


Book ID
120540356
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
989 KB
Volume
23
Category
Article
ISSN
0020-1669

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The rates of oxidation of four a-keto acids, glyoxylic, pyruvic, phenylglyoxylic, and 2oxobutyric acids by Cerium(1V) in H2S04-HaHS04 and HzS04-HC104 solutions, have been studied spectrophotometrically. The rate data suggest that CeSO:' is the most reactive of the Cerium(1V)-sulfate complexes presen