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Study of vanadium(IV) species and corresponding electrochemical performance in concentrated sulfuric acid media

✍ Scribed by Xuewen Wu; Jinjin Wang; Suqin Liu; Xiongwei Wu; Sha Li

Book ID: 113596417
Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 837 KB
Volume: 56
Category: Article
ISSN: 0013-4686
DOI: 10.1016/j.electacta.2011.09.006

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## Abstract The kinetics and mechanism of cerium(IV) oxidation of hexitols, i.e. D‐sorbitol and D‐mannitol, in aqueous sulfuric acid media have been studied in the presence and absence of surfactants. Under the kinetic conditions, [S]~T~ ≫ [Ce(IV)]~T~, where [S]~T~ is the total substrate (D‐sorbito