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Dimeric dioxocations, (NpO2+)2, in the structure of bis­(μ-2-fluoro­benzoato-κ2O:O′)di-μ-oxo-bis­[(2,2′-bipyridine-κ2N,N′)oxoneptunium(V)]

✍ Scribed by Grigoriev, Mikhail S. ;Krot, Nikolai N. ;Bessonov, Alexei A. ;Suponitsky, Kyrill Yu.


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
202 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


Dimeric dioxocations, (NpO 2 + ) 2 , in the structure of bis(l-2-fluorobenzoato-j 2 O:O 0 0 0 )di-l-oxobis[(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )oxoneptunium(V)]


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✍ Zhang, Bing-Yu ;Xu, Tu-Gen ;Xu, Duan-Jun 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 379 KB

The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co