Dimeric dioxocations, (NpO2+)2, in the structure of bis(μ-2-fluorobenzoato-κ2O:O′)di-μ-oxo-bis[(2,2′-bipyridine-κ2N,N′)oxoneptunium(V)]
✍ Scribed by Grigoriev, Mikhail S. ;Krot, Nikolai N. ;Bessonov, Alexei A. ;Suponitsky, Kyrill Yu.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 202 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Dimeric dioxocations, (NpO 2 + ) 2 , in the structure of bis(l-2-fluorobenzoato-j 2 O:O 0 0 0 )di-l-oxobis[(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )oxoneptunium(V)]
📜 SIMILAR VOLUMES
Di-l-acetato-j 4 O:O 0 0 0 -bis[bis(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )manganese(II)] bis(perchlorate)
The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co