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Dimer formation in the reaction of aryl halides catalyzed by nickel complexes

✍ Scribed by Yu. G. Budnikova; Yu. M. Kargin; V. V. Yanilkin

Book ID
112424169
Publisher
Springer
Year
1992
Tongue
English
Weight
183 KB
Volume
41
Category
Article
ISSN
1573-9171

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Mild and selective reductions of aryl ha
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✍ Bruce H. Lipshutz; Takashi Tomioka; Steven S. Pfeiffer πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 229 KB

Treatment of aryl chlorides with catalytic amounts of (PPh 3 ) 2 NiCl 2 +PPh 3 in the presence of an equivalent of Me 2 NHβ€’BH 3 and either K 2 CO 3 or Cs 2 CO 3 in CH 3 CN under mild conditions leads to the corresponding product of reduction. Aryl bromides and iodides can also be reduced, selectivel