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Diisopropyl (hydroxy­phenyl­meth­yl)phospho­nate

✍ Scribed by Fang, Hua ;Fang, Mei-Juan ;Luo, Shu-Na ;Huang, Rong-Bin ;Zhao, Yu-Fen

Book ID
104486343
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
227 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, C 19 H 22 ClN 4 O 5 PS, the P atom adopts a distorted tetrahedral configuration. Intra-and intermolecular C-HÁ Á ÁO hydrogen bonds, together with weak C-HÁ Á Á hydrogen bonding and strongstacking interactions, stabilize the crystal structure.

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The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-

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