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Dihydroxyacetone dimers; solution and crystal structure of stereoisomers of 2,5-diethoxy-1,4-dioxane-2,5-dimethanol

โœ Scribed by Viggo Waagen; Tilak K Barua; Henrik W Anthonsen; Lars K Hansen; Dag-J Fossli; Edward Hough; Thorleif Anthonsen

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
349 KB
Volume
50
Category
Article
ISSN
0040-4020

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Studies on the unusual stability of cis-
Studies on the unusual stability of cis-2,5-diethoxy-2,5-bis(hydroxymethyl)-1,4-dioxane
โœ Hideya Yuasa; Hironobu Hashimoto; Yutaka Abe; Tetsuya Kajimoto; Chi-Huey Wong ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 513 KB

Almost equal amounts of the trans and cis isomers of 2,5-diethoxy-2,5-bis(hydroxymethyl)-1,4dioxane (2trans and 2cis) are obtained by treating dihydroxyacetone with acidic ethanol. To explain the formation of an unusually large quantity of 2cis, conformation analyses and equilibration experiments we