## Abstract Anionic polymerizations with an anthracene‐derived initiator are described as giving rise to polymers containing only one chromophore on each chain. The approach taken herein involves the deprotonation of dihydroanthracene (1) and the initiation of methyl methacrylate, vinylpyridine and
Dihydroanthracene dimers as novel bifunctional initiators for anionic polymerization
✍ Scribed by Th. Bartz; M. Klapper; K. Müllen
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 385 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0323-7648
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📜 SIMILAR VOLUMES
Lanthanum isopropoxide was found to serve as a novel anionic initiator for the polymerization of hexyl isocyanate affording poly(hexy1 isocyanate) with very high molecular weight (M, > lo6) under appropriate conditions. Other lanthanoid alkoxides, such as samarium, ytterbium and yttrium isopropoxide
## Abstract Anionic‐coordinative polymerization of methyl methacrylate (MMA) was carried out in the presence of new bimetallic initiators based on lithium alkylnickelates and alkylpalladates in tetrahydrofuran, at −78°C. Well‐defined poly(methyl methacrylate), PMMA, with molecular weights increasin