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Dihydro-1,3-oxazines. XII. The oxazine α-carbanion-ketenimine rearrangement.

✍ Scribed by A.I. Meyers; Elizabeth M. Smith

Publisher: Elsevier Science
Year: 1970
Tongue: French
Weight: 203 KB
Volume: 11
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89484-8

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✦ Synopsis

The reaction of metallated Z-methyl (A) and E-benzyl e) dihydro-1,3-oxazines with electrophilic reagents (e.g. n-amyl iodide) producing alkylated derivatives (j and 2) which ultimately lead to aldehydes Q and 8) has been recently reported. 2 However, when the 2-

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