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Difluoro(trifluoromethylsulfenylimino)sulfur CF3SNSF2 and Bis(trifluoromethylsulfenylimino)sulfur CF3SNSNSCF3

โœ Scribed by Doz. Dr. A. Haas; Dipl.-Chem. P. Schott


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
233 KB
Volume
6
Category
Article
ISSN
0044-8249

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1,2-Bis[trifluorosulfur(IV)]tetrafluoroe
โœ Detlef Viets; Werner Heilemann; Enno Lork; Rรผdiger Mews; Wolf-Dieter Stohrer; To ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 278 KB

The title compound (-CF 2 -SF 3 ) 2 ( 2) is prepared from (-CF 2 -SO 2 gives [-CF 2 -S(O)F] 2 (4), and CsF-catalysed oxidation with F 2 leads to the previously reported (-CF 2 -SF 5 ) 2 ( 11). Ab SCl) 2 (1) and F 2 at -90 ยฐC in 83 % yield. Reaction of 2 with CsF and TASF yields Cs[(-CF 2 -SF 3 ) 2 F