On p. 239, Eq. (11) should read: f(+) =+&))-l(&j)l'd exp (-&j).
Diffusional effects in reacting mixtures
โ Scribed by Sudhir V. Golikeri; Dan Luss
- Book ID
- 103005261
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 480 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0009-2509
No coin nor oath required. For personal study only.
โฆ Synopsis
The determination of the effectiveness factor for a mixture in which many parallel reactions occur is analyzed. It is shown that the exact determination of E.F. requires information about the distribution of the rate constants which is usually not available due to analytical difficulties. However, a rather accurate estimate can be obtained from two measurable quantities-the overall rate and its relative dispersion. In case of first order reactions, the maximal uncertainty involved in the estimate can be predicted for any mixture.
๐ SIMILAR VOLUMES
It is shown that strongly non-ideal chemical reactions, exhibiting multiple equilibrium states, can occur only in the dfffusionally unstable region in the interior of the usual spinodal curve. The possibility of observing the effect of chemical nonideality in the homogeneous single-phase region near