The concept of a diffusion coefficient dependent on a differential fractal dimension has been introduced into the theoretical treatment of diffusion-controlled reactions between particles lacking long-range interactions. By this means Smoluchowski's theory can be extended to the more realistic case
Diffusion-controlled reactions on an active site
✍ Scribed by A.B. Doktorov; N.N. Lukzen
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 357 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The rate constant of a diffusion-controlled reaction on a small active site has been obtamed usmg the accurate nnJlytlca1 solution The result derrved has been compared wth the approumate formula available m the hterature and also wth the expression on the basis of a recently proposed simple kmetlc conslderatton.
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