๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Diffusion coefficient measurements by solvent absorption in concentrated polymer solution

โœ Scribed by Charles M. Hansen


Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
264 KB
Volume
26
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

โœฆ Synopsis


Abstract

Diffusion coefficient measurements for solvents in concentrated polymer solutions require consideration of both concentration dependence of the diffusion coefficient and surface resistance to mass transport. Solutions to the diffusion equation have been generated where these effects are explored. A method to account for both concentration dependence and surface (absorption) resistance in the experimental determination of diffusion coefficients is given and demonstrated with an example where a multiplying factor of over 300 is required to adjust the apparent diffusion coefficient to the value sought.


๐Ÿ“œ SIMILAR VOLUMES


Prediction of solvent-diffusion coeffici
โœ W. H. Jiang; R. Han ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 190 KB ๐Ÿ‘ 2 views

Several versions of free-volume theory have been proposed to correlate or predict the solvent diffusion coefficient of a polymer/solvent system. The quantity of free volume is usually determined by the Williams-Landel-Ferry (WLF) equation from viscosity data of the pure component in these theories.

Simultaneous measurements of the electro
โœ Axel Ekani Nkodo; Bernard Tinland ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 177 KB ๐Ÿ‘ 2 views

We determined simultaneously the electrophoretic mobility, diffusion coefficient D and molecular orientation during electrophoresis of dsDNAs in polymer solutions ranging from the dilute to the semidilute regime. We established, for the first time, master scaling laws for the diffusion coefficient s