Diffusion and disequilibrium for rapid bimolecular reactions in solution: influence of the back-reaction
✍ Scribed by Keizer, Joel
- Book ID
- 118214274
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 783 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
A formulation of the theory for diffusion influenced reversible reaction A+BX in solution is used to study the effect of the back reaction on the bimolecular forward rate coefficient. The formula recently derived by Szabo that relates the forward rate coefficient in the presence of the back reaction
## Abstract Cyano‐substituted methyl radicals (cyanomethyl–hand 2‐cyano‐2‐propyl radicals) and __syn__‐and __anti__‐1‐cyano‐allyl radicals were generated, and their recombination kinetics in solution were investigated between −50 and +50°C by time‐resolved electron‐spin‐resonance spectroscopy. The